All LC–MS chromatograms were being chosen for your theoretical m/z values of the respective compounds of fascination (Extended Info Desk three). a, As opposed by using a strain that lacks the olivetolic acid synthesis pathway (yCAN14), yCAN32 created a further compound with the m/z value similar to divarinolic acid (DA). The retention time of divarinolic acid is lowered relative to olivetolic acid, owing to your reduced hydrophobicity that is definitely conferred from the shorter 5-propyl side chain.
Miller B, Madilao LL, Ralph S, Bohlmann J. Insect induced conifer defense. White pine weevil and methyl jasmonate induce traumatic resinosis, denovo shaped volatile emissions and accumulation of terpenoid synthase and putative octadecanoid pathway transcripts in Sitka spruce.
Equally, merely a free correlation involving terpenoid pathway gene expression and enzyme exercise has long been present in Ocimum
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) terpene synthases tend to be more closely related to each other than to some other oxidosqualene cyclases they usually along with the Panax ginseng
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species. Because feeding of herbivores alters the aromatic profile of important oil-making plants like Mentha aquatica
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Jasmonate was documented for being basic inducer of biosynthesis of plant secondary metabolite (Memelink et al. 2001; van der Suits and Memelink 2000). Jasmonate and its spinoff methyl jasmonate were being proven to induce the terpenoid indole biosynthesis in suspension mobile cultured with auxin and to boost the terpenoid indole alkaloid production when cells had been cultured in an auxin-free of charge medium (Gantet et al. 1998). Genes involved in secologanin biosynthesis (